Levels and distribution of polybrominated diphenyl ethers and organochlorine compounds in sea turtles from Japan     

Malarvannan G  Takahashi S  Isobe T  Kunisue T  Sudaryanto A  Miyagi T  Nakamura M  Yasumura S  Tanabe S 《Marine pollution bulletin》2011,63(5-12):172-178

Three species of sea turtles (green, hawksbill and loggerhead turtles) stranded along the coasts or caught (by-catch) around Ishigaki Island and Kochi, Japan were collected between 1998 and 2006 and analyzed for six organohalogen compounds viz., PBDEs, PCBs, DDTs, CHLs, HCHs and HCB. The present study is the first and foremost to report the occurrence of organohalogen compounds in the sea turtles from Japan. Among the compounds analyzed, concentrations of PCBs, DDTs and CHLs were the highest in all the turtle samples. PBDEs were ubiquitously present in all the turtle species. Comparing with the other two species, concentrations of organohalogens in green turtle were relatively low and decreasing trend in the concentrations were noted with increasing carapace length. Concentrations of OCs in sea turtles from the coasts of Ishigaki Island and Kochi were relatively low as compared to those from other locations in the world.  相似文献   

Marine meiobenthic and nematode community structure in Victoria Harbour, Hong Kong upon recovery from sewage pollution     

Liu XS  Xu WZ  Cheung SG  Shin PK 《Marine pollution bulletin》2011,63(5-12):318-325

Sediment quality, meiofaunal and nematode communities were monitored across six time points at two inside-harbour and three outside-harbour sites over a three-year period in Victoria Harbour, Hong Kong, after the implementation of a sewage treatment project. Twenty-one meiofaunal groups comprising mainly free-living nematodes and harpacticoid copepods and 188 species of free-living nematodes were identified. The outside-harbour area had a more diverse and significantly different nematode community structure as compared to that in the inside-harbour area. Such spatial difference was highly correlated with the total Kjeldahl nitrogen content of the sediments. Over the study period, there was no significant improvement in sediment quality within the harbour. However, in the last sampling time, an increase in meiofaunal abundance and a closer similarity in nematode composition between one of the inside- and outside-harbour sites suggested signs of recovery of the meiofauna as a response to abatement of sewage pollution.  相似文献   

Temperature trends in the skin/surface, mid-troposphere and low stratosphere near Korea from satellite and ground measurements     

Jung-Moon Yoo  Young-In Won  Young-Jun Cho  Myeong-Jae Jeong  Dong-Bin Shin  Suk-Jo Lee  Yu-Ri Lee  Soo-Min Oh  Soo-Jin Ban 《Asia-Pacific Journal of Atmospheric Sciences》2011,47(5):439-455

Various types of satellite (AIRS/AMSU, MODIS) and ground measurements are used to analyze temperature trends in the four vertical layers (skin/surface, mid-troposphere, and low stratosphere) around the Korean Peninsula (123–132°E, 33–44°N) during the period from September 2002 to August 2010. The ground-based observations include 72 Surface Meteorological Stations (SMSs), 6 radiosonde stations (RAOBs), 457 Automatic Weather Stations (AWSs) over the land, and 5 buoy stations over the ocean. A strong warming (0.052 K yr^?1) at the surface, and a weak warming (0.004～0.010 K yr^?1) in the mid-troposphere and low stratosphere have been found from satellite data, leading to an unstable atmospheric layer. The AIRS/AMSU warming trend over the ocean surface around the Korean Peninsula is about 2.5 times greater than that over the land surface. The ground measurements from both SMS and AWS over the land surface of South Korea also show a warming of 0.043～0.082 K yr^?1, consistent with the satellite observations. The correlation average (r = 0.80) between MODIS skin temperature and ground measurement is significant. The correlations between AMSU and RAOB are very high (0.91～0.95) in the anomaly time series, calculated from the spatial averages of monthly mean temperature values. However, the warming found in the AMSU data is stronger than that from the RAOB at the surface. The opposite feature is present above the mid-troposphere, indicating that there is a systematic difference. Warming phenomena (0.012～0.078 K yr^?1) are observed from all three data sets (SMS, AWS, MODIS), which have been corroborated by the coincident measurements at five ground stations. However, it should also be noted that the observed trends are subject to large uncertainty as the corresponding 95% confidence intervals tend to be larger than the observed signals due to large thermal variability and the relatively short periods of the satellitebased temperature records. The EOF analysis of monthly mean temperature anomalies indicates that the tropospheric temperature variability near Korea is primarily linked to the Arctic Oscillation (AO), and secondarily to ENSO (El Niño and Southern Oscillation). However, the low stratospheric temperature variability is mainly associated with Southern Oscillation and then additionally with Quasi-Biennial Oscillation (QBO). Uncertainties from the different spatial resolutions between satellite data are discussed in the trends.  相似文献   

Mixing of magmatic CO₂ into volcano groundwater flow at Aso volcano assessed combining carbon and water stable isotopes     

Makoto Yamada  Shinji Ohsawa  Kohei Kazahaya  Masaya Yasuhara  Hiroshi Takahashi  Kazuhiro Amita  Hideo Mawatari  Shin Yoshikawa 《Journal of Geochemical Exploration》2011

To understand deep groundwater flow systems and their interaction with CO₂ emanated from magma at depth in a volcanic edifice, deep groundwater samples were collected from hot spring wells in the Aso volcanic area for hydrogen, oxygen and carbon isotope analyses and measurements of the stable carbon isotope ratios and concentrations of dissolved inorganic carbon (DIC). Relations between the stable carbon isotope ratio (δ¹³C_DIC) and DIC concentrations of the sampled waters show that magma-derived CO₂ mixed into the deep groundwater. Furthermore, groundwaters of deeper areas, except samples from fumarolic areas, show higher δ¹³C_DIC values. The waters' stable hydrogen and oxygen isotope ratios (δD and δ¹⁸O) reflect the meteoric-water origin of that region's deep groundwater. A negative correlation was found between the altitude of the well bottom and the altitude of groundwater recharge as calculated using the equation of the recharge-water line and δD value. This applies especially in the Aso-dani area, where deeper groundwater correlates with higher recharge. Groundwater recharged at high altitude has higher δ¹³C_DIC of than groundwater recharged at low altitude, strongly suggesting that magmatic CO₂ is present to a much greater degree in deeper groundwater. These results indicate that magmatic CO₂ mixes into deeper groundwater flowing nearer the magma conduit or chamber.  相似文献   

Environmentally associated spatial changes of a macrozoobenthic community in the Saemangeum tidal flat,Korea     

Jongseong Ryu  Jong Seong Khim  Jin-Woo Choi  Hyun Chool Shin  Soonmo An  Jinsoon Park  Daeseok Kang  Chang-Hee Lee  Chul-Hwan Koh 《Journal of Sea Research》2011,65(4):390-400

Estuarine tidal flats are both ecologically and economically important, hence developing methods to reliably measure ecosystem health is essential. Because benthic fauna play a central role in the food web of tidal flats, in this study we set out to quantitatively describe the intertidal zonation of macro-invertebrates and their associations with specific environmental parameters along three transects in the Saemangeum tidal flat, Korea. The abundance and biomass of intertidal fauna with respect to five environmental parameters (i.e., shore level, mud content, coarse sand content, water content, and organic content) were measured, to identify environmental factors that influence macrofaunal distribution in intertidal soft bottom habitats. A total of 75 species were identified, with dominant species showing distinct zones of distribution along all transects. The number of species recorded in each transect was found to be dependent on sediment characteristics and salinity. Cluster analysis classified the entire study area into three faunal assemblages (i.e., location groups), which were delineated by characteristic species, including (A) ‘Periserrula–Macrophthalmus’, (B) ‘Umbonium–Meretrix’, and (C) ‘Prionospio–Potamocorbula’. Four environmental variables (i.e., shore level, water content, mud content, and organic content) appeared to determine factors that distinguished the three faunal assemblages, based on the discriminant analysis. The faunal assemblage types of the sampled locations were accurately predicted from environmental variables in two discriminant functions, with a prediction accuracy of 98%. It should be noted that the zonation of benthos in the lower section (C) of Sandong had been affected by the construction of a nearby dike, while this parameter had remained essentially unchanged at the other two location groups (A–B). Overall, the zonation of benthos from the Saemangeum tidal flat was explained adequately by the measured environmental variables, implying that faunal assemblages are closely associated with certain combinations of abiotic factors. The identification of such reliable associations may facilitate the development of statistical models to predict faunal distributions based on environmental variables at both local and regional scales. The entire study area was embanked in 2006 (one year after this study), and an integrated plan was set into force to develop claimed land into industrial, residential and agricultural districts, which also included a partial restoration program of the tidal flats located near to the study area.  相似文献   

Geochemistry and geochronology of meta-igneous rocks from the Tokat Massif, north-central Turkey: implications for Tethyan reconstructions     

Elizabeth J. Catlos  Kathryn Huber  Timothy A. Shin 《International Journal of Earth Sciences》2013,102(8):2175-2198

Located in the eastern Pontides of the Sakarya Zone in north-central Turkey, the Tokat Massif records the closure of both the Paleo-Tethyan (Karakaya Complex) and Neo-Tethyan ocean basins. Meta-igneous samples collected from the region were studied to determine their sources and ages. We find significant geochemical differences between metagabbros of the Karakaya and Neo-Tethyan units in terms of their trace elements: Neo-Tethyan rocks are consistent with generation in an island arc setting, whereas Karakaya assemblages were likely generated in an oceanic spreading-center environment. Karakaya metagabbros also contain glaucophane, consistent with subduction subsequent to formation. Small (2–50 μm) zircon and baddeleyite grains from four Karakaya metagabbros were dated in thin section using an ion microprobe. The results demonstrate the reliability of the method to directly constrain the tectonomagmatic history of these types of assemblages. The rocks yield Late Permian/Early Triassic ²³⁸U/²⁰⁶Pb crystallization ages of 258 ± 14 Ma (±1σ, zircon) and 254 ± 8 Ma (±1σ, baddeleyite) and an Early Cretaceous minimum metamorphic age of 137 ± 8 Ma (±1σ, zircon). Some zircon grains and baddeleyite grains with zircon overgrowths yield Early to Middle Jurassic ages. Here we present a model in which metamorphism and deformation in this region occurred during northward subduction and closure of a Paleo-Tethyan ocean basin and accretion of the Karakaya units to the Laurasian continental margin. This was followed by the onset of closure of the Neo-Tethys during the Campanian-Paleocene and accretion of island arc units to the Tokat region.  相似文献   

Simultaneous stabilization of arsenic, lead, and copper in contaminated soil using mixed waste resources   总被引：1，自引：0，他引：1  

Keun-Young Lee  Deok Hyun Moon  Sang-Ho Lee  Kyoung-Woong Kim  Kyung-Hoon Cheong  Jeong-Hun Park  Yong Sik Ok  Yoon-Young Chang 《Environmental Earth Sciences》2013,69(6):1813-1820

In the present study, stabilization treatment using waste resource stabilizers was performed for soil contaminated with As and heavy metals (Pb and Cu). Calcined oyster shell (COS) and coal mine drainage sludge (CMDS) were used as a mixed stabilizing agent for a wet-curing duration of 28 days. After the stabilization treatment, the treatment process efficiency was evaluated by the results of various batch- and column-leaching tests. Neutral and weak acid extraction methods, such as water-soluble extraction and SPLP, did not exhibit satisfactory results for heavy metal stabilization, even if they showed very low leachability. On the other hand, TCLP and 0.1 M HCl extraction showed that the stabilizers significantly reduced the amount of heavy metals leached from the soil, which strongly supports the thesis that the stabilization treatment is efficient in the acidic leaching conditions that were explored. Specifically, in the 0.1 M HCl extraction, the reduction efficiencies of As, Pb, and Cu leachings were more than 90 %, compared with control experiments. This study demonstrates that the application of waste resources for the stabilization of As and heavy metals is feasible. However, some limitations observed in the experiments should be considered in future studies, such as the mobilization of alkali-soluble elements, and in particular, exchangeable fractions of Cu. In addition, the treatment efficiency can be evaluated by different leaching methods, which suggests that multidirectional approaches are required for the proper evaluation of stabilization treatment.  相似文献   

Spatio-temporal changes of marine macrobenthic community in sub-tropical waters upon recovery from eutrophication. I. Sediment quality and community structure   总被引：1，自引：0，他引：1  

Shin PK  Lam NW  Wu RS  Qian PY  Cheung SG 《Marine pollution bulletin》2008,56(2):282-296

A two-year study was conducted in the vicinity of a harbour in sub-tropical Hong Kong, to examine the progress of improvement in sediment quality and recovery of macrobenthic community upon cessation of organic pollution caused by sewage discharge. Median sediment particle diameter (Mdphi) and levels of total organic carbon (TOC), total Kjeldahl nitrogen (TKN), ammonia-nitrogen (NH(3)-N) and total phosphorus (TP), as well as macrobenthic species composition and abundance were determined bi-monthly at three inside-harbour and two outside-harbour locations. At the two inside-harbour locations, significantly higher levels of TOC, TKN, NH(3)-N and TP in sediments were observed than the outside-harbour locations. However, no significant temporal change of nutrient levels was detected at all sampling locations during the two-year study, except a significant decrease in TKN and NH(3)-N levels at one outside-harbour location and a decline in NH(3)-N content at another outside-harbour location. Spatially, the highest in mean total species number, individual number, species diversity H' and lowest evenness J was found at one outside-harbour location, whereas the other four locations had relatively similar values. H' was negatively correlated with TOC, TKN, NH(3)-N and TP content in sediments while J was positively correlated with MDphi. Across the study period, the patterns of macrobenthic community were significantly different among all samplings and that the spatial difference of benthic community was best correlated with MDphi, TOC, TKN and water depth. A weak sign of recovery in macrobenthic community structure was detected at inside-harbour locations, with replacement of opportunistic by ubiquitous species over the two-year study. The slow recovery of macrobenthic community was related to sediment characteristics. Results of a larval settlement bioassay using the polychaete Capitella sp. I also demonstrated that the inside-harbour sediments were still unfavourable for colonization and larval settlement of species sensitive to pollution. The slow biodegradation of the organic pollutants and continuous presence of heavy metals in the sediment may hinder settlement and colonization of benthic animals. However, increases of H' and J were observed in a longer time scale when comparing the present data with those obtained four years ago. This suggested that a detectable recovery of benthic community in the harbour may take at least three years and a complete recovery may even take longer duration.  相似文献   

A tribute to John Stuart Gray (1941-2007)     

Richardson B  Wu R  Shin P  Lam P  Fleddum A  Elliott M  Sheppard C 《Marine pollution bulletin》2008,56(1):1-4

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Effect of prolonged hypoxia on food consumption, respiration, growth and reproduction in marine scavenging gastropod Nassarius festivus     

Cheung SG  Chan HY  Liu CC  Shin PK 《Marine pollution bulletin》2008,57(6-12):280-286

The effects of prolonged exposure to reduced oxygen levels (3.0 and 1.5 mg O(2)l(-1)) on marine scavenging gastropods Nassarius festivus were studied for 8 weeks. The percentages of individuals engaged in feeding and amount of food consumed were reduced as oxygen level decreased; absorption efficiency, however, did not vary significantly with oxygen level. Oxygen consumption rates and specific oxygen consumption rates were lower at reduced oxygen levels. Reproduction occurred at all oxygen levels with less egg capsules being produced at lower oxygen levels. Egg size and number of eggs per capsule, however, were not significantly affected by oxygen level. The increase in shell length was 12%, 6% and 5% at 6.0 mgO(2)l(-1) (normoxia), 3.0 mgO(2)l(-1) and 1.5 mgO(2)l(-1), respectively. At the end of the experiment, the amount of energy allocated to growth and reproduction decreased at reduced oxygen levels with values obtained at 3.0 mgO(2)l(-1) and 1.5 mgO(2)l(-1) being 48% and 70% lower than those at 6.0 mgO(2)l(-1). At all oxygen levels, most of the accumulated energy was allocated to shell growth and reproduction, and the amount allocated to somatic growth was relatively insignificant. The reduction in energy allocated to reproduction was greater than that to shell growth as the oxygen level was reduced, indicating a strategic energy allocation of marine scavengers under stressful conditions to enhance survival.  相似文献